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HCB in Botany

We need your Help to Stop the Export of Australia's stockpile of hexachlorobenzene (HCB) waste to Europe for incineration!

Orica Australia Pty Ltd (formerly ICI Australia) is proposing to export 11,000 tonnes of highly toxic hexachlorobenzene waste to Europe for incineration. Help us stop this unnecessary export and ensure that the stockpile is destroyed by non incineration methods in Australia.

In 1996 the Australian National Advisory Body (NAB) on Scheduled Waste released the national Management Plan for Hexachlorobenzene (HCB) to oversee the destruction of the HCB waste stockpile. The plan recommended that the waste should be destroyed as "close to the source as possible" in the light of the significant risk in transporting such a large stockpile of persistent organic pollutant (POPs) waste and Australia's proven ability to destroy hazardous waste in an environmentally sound manner.

After many years of failing to address its hazardous waste responsibilities, the company rejected the well tried, community supported technology, ECOLOGIC Gas Phase Chemical Reduction (GPCR) Process. Its choice instead of an untried, semi incineration vitrification process led to local community concern and the rejection of its Environmental Impact Statement. The company has now been directed by the NSW Commission of Inquiry to find an alternative site in the state of New South Wales.

Orica's current proposal to export the 11,000 tonnes of HCB waste to an incinerator overseas is in breach of both the intention and spirit of the HCB Management Plan and contravenes the principles of environmentally sound management of hazardous waste as developed by the UN Secretariat of the Basel Convention on the Control of Transboundary Movements of Hazardous Wastes & their Disposal (1989). These include :

f) the self-sufficiency principle - management and disposal of waste in the country where it was created

g) the proximity principle - the disposal of hazardous waste as close as possible to their point of generation

h) the least transboundary movement principle - transboundary movements of hazardous waste reduced to a minimum

We are asking the Australian Minister for the Environment to accept the principle that Australia takes responsibility for the environmentally-sound destruction of its own HCB waste, as it has done for all previously generated POPs waste.

If you agree that Australia should be responsible for its own waste and not export this stockpile to Europe for incineration, please download the letter of protest (Adobe Acrobat file 18KB) and email to the Australian Minister for the Environment and Heritage, Senator the Hon. Ian Campbell. senator.ian.campbell@aph.gov.au


Background to the HCB Stockpile

For over two decades, the chemical company, Orica Australia Pty Ltd (formerly ICI Australia) produced a large quantity of hexachlorobenzene (HCB) waste. This industrial waste was an unwanted byproduct from the manufacture of chemical solvents and was never used by Orica for commercial purposes. Approximately 10,500 tonnes of HCB waste is now stored at Orica site in the Botany Industrial Park in Sydney NSW awaiting destruction. The site is surrounded by residential suburbs. Unfortunately, HCB is difficult to destroy.

HCB waste is considered a 'schedule waste' because it is organic in nature, (i.e., its based on carbon molecules); resistant to degradation (breakdown) by chemical, physical or biological means; toxic to humans, vegetation or aquatic life, and bioaccumulates in humans, flora and fauna.  The destruction of the HCB is the focus of the National HCB Scheduled Waste Management Plan.

Studies in animals have shown that eating HCB for a long time can damage the liver, thyroid, nervous system, bones, kidneys, blood, and immune and endocrine systems. The immune systems of rats that breathed HCB for a few weeks were harmed and the U.S. Department of Health and Human Services (DHHS) has determined that HCB may reasonably be expected to be a carcinogen. HCB is found throughout the environment and is regularly detected in the blood, breast milk and fats of humans and wildlife. While much of the HCB contamination has come from diverse sources such as HCB based agricultural chemicals and industrial emissions, the stored HCB waste presents an ongoing risk that needs to be addressed.

HCB does not dissolve in water very well, so most of it remains in particles on the bottom of lakes and rivers allowing high levels to build up in fish, marine mammals and birds. It also adheres strongly to soil and can accumulate in wheat, grasses, some vegetables and plants.

Most people are exposed to HCB through eating low levels in contaminated food such as contaminated fish, milk or dairy products or meat from cattle grazing on contaminated pastures. People can also be exposed through drinking contaminated water or by breathing low levels in contaminated air, eating or touching contaminated soil or working at a factory that uses or produces HCB unintentionally. Drinking contaminated breast milk from exposed mothers is a significant source of HCB for babies.

As HCB breaks down very slowly, remaining in the environment for a long time and is dispersed across the globe by both air and water, the international community has included HCB on their target list of persistent organic pollutants or POPs. Through the United Nations Environment Program, the countries of United Nations have cooperatively developed a global treaty to phase out and eliminate persistent organic pollutants. The POPs Convention came into force in May 2004.


There are two main types of HCB wastes stored at Botany, they are the principal HCB waste stored in drums and tanks and the encapsulated 'car park' waste, consisting of approximately 45, 000 cubic meters of contaminated sand and coal ash.

The treatment of these different types of waste requires different approaches. Orica has reviewed a range of destruction technologies for the drummed waste.
Orica carried out preliminary design work and cost estimates for a destruction facility plant for the stockpiled drummed HCB waste, stored at the Botany Industrial Park.

This work focused on the two technologies selected for trials :

  • GEOMELT Vitrification Process
  • ECOLOGIC Gas Phase Chemical Reduction (GPCR) Process.


  • Both technologies could be used either on site or off site. Orica made its final selection of GeoMelt in November 2000.

    NGOs and community groups have opposed both the technology choice and the destruction on site. While the Minister for the Environment gave approval to the choice of technology, he has directed Orica to find a more suitable site for the destruction of the largest HCB stockpile in the world.

    Contaminated Groundwater Plume

    In late August 2003, the New South Wales Environment Protection Authority (NSWEPA) decided to issue Orica (Botany) Pty Ltd with a Clean Up Notice under the Protection of the Environment Operations Act (POEO). It requires Orica (formerly ICI Australia) to clean up the contaminated ground water plume originally emanating from their industrial site at Botany and now covering approximately two square kilometres.

    Earlier in 2004, Orica had submitted their report to the NSW EPA under the Voluntary Investigation and Remediation agreement. The report noted that there were high levels of EDC or 1,2 -Dichloroethane in the deep aquifer beneath Orica’s ‘Southlands’. The center of the EDC plume where levels are greater than 5,000 milligrams per litre is moving as a ‘slug’ with its axis shifting further east than previously modelled.

    In the report Orica also noted that levels of other contaminants tetrachloroethylene (PCE) and trichloroethylene (TCE) were increasing at the monitoring point at the Penrhyn Estuary, which empties into Botany Bay. Other monitoring points for the northern plume also showed increases in the levels of carbon tetrachloride (CTC).

    This group of chlorinated hydrocarbon chemicals nearly all have the potential to cause cancer and affect reproductive and developmental health. EDC is suspected of being capable of causing heritable genetic and chromosomal mutations.

    Despite Orica’s voluntary investigations into remediation of the plumes, the NSW EPA has now ordered Orica to ‘treat and pump’; ie, to extract the contaminated ground water and treat it with an appropriate technology, according to best international practice and in line with national guidelines.

    The NSW EPA stated that the move to issue orders came after tests confirmed that the contamination levels in groundwater from Orica’ s site were spreading at a faster pace than was previously known.ICI Australia has produced chlorine and the intermediaries for poly vinyl chloride (PVC) on the Botany site since the 1940s and for the 30 years from the 1960s to 1990 carbon tetrachloride was also manufactured. In 1989 ICI was directed by the then State Pollution Control Commission (now the NSW EPA) to investigate contamination of groundwater in their area. They carried out the Botany Groundwater Survey Stage 1 which was released in May, 1990.

    The investigations reported that the both shallow and deep groundwater was contaminated with chlorinated hydrocarbons like tetrachloroethylene (PCE), trichloroethane (TCA) and trichloroethylene (TCE) as well as the persistent organic pollutant, hexachlorobenzene (HCB). EDC was detected at around 150 mg/l in both shallow and deep groundwater.

    Mercury and chromium were also discovered in the sediments of Springvale Drain running through the site, while both mercury and HCB were detected in biological samples from the Penrhyn Estuary, exceeding national guidelines.

    Importantly, the 1990 report found that the deep plume could be moving through the sand layers at approximately 60 to 210 metres per year.

    A Stage 2 survey, instigated to more clearly define the nature and extent of groundwater contamination and to develop and evaluate remediation options was released six years later in 1996. It confirmed that groundwater contaminants linked to past industrial activities were in both shallow and deep groundwater.
    It confirmed six major source areas of contamination:

  • The former solvent plant;
  • EDC Storage tanks;
  • Former CTC Storage tank (polythene);
  • Filled areas adjacent to the railway line;
  • Old 'heavy ends' drum storage area; and
  • Old surface drain.

    The Stage 2 survey provided 1994 sampling data showing levels of EDC in deep groundwater of 6,800 mg/l and 6,300 mg/l in shallow groundwater in the area of the old EDC storage tanks. It was estimated that the plumes were moving in a south to south westerly direction at around 70 to 80 metres per year in the upper layers and 3 to 4 metres per year at deeper levels. Assessments of health risks carried out by Orica concluded that the contamination had not created any unacceptable risk to human health.

    The Stage 2 survey identified the possible remediation options including the Reactive Barrier Technology, which Orica is currently investigating and trialing. It is permeable trench filled with iron filings installed below-ground to intercept and passively destroy contaminants in shallow groundwater as they pass through the barrier. Results collected in June 1999 from a Reactive Barrier prototype to treat shallow groundwater indicate up to 89% destruction of total chlorinated hydrocarbons. Other options include in situ bioremediation and the range of pump and treat technologies.

    However, all remediation options are listed as having a “very large” timescale, which is measured in decades. The report notes that a ‘pump and treat’ exercise on the Orica plumes could take up to a century. At the recent public meeting held in Botany (10/9/2003), the NSW EPA claim that cleanup to drinking water standards is possible within 15 years.

    In 2004, residents in the affected area were contacted by the NSW EPA and the Department of Infrastructure Planning and Natural Resources (DIPNR) advising them not to use bore water.

    Of concern to many is the ongoing commitment of Orica Australia to the Botany site. The company is responsible for a stockpile of 10,500 tonnes of HCB drummed waste, stored at the Botany site. The stockpile awaits destruction at an estimated cost of over $80 million. The company on the face of it seems over the years to have been winding back its presence at Botany.The recent clean up order and publicity over the groundwater plume emanating from the Botany Industrial Park exemplifies serious questions about future financial liability.

    Consideration of the company’s potential liability for groundwater contamination may make the estimated $80 million cost for HCB destruction look quite small. For these reasons, it would be very appropriate for the NSW Government to immediately secure a bond from Orica to cover the cost of HCB destruction and other remediation in the very near future. Failure to ensure this could potentially see the citizens of NSW left not only with the legacy of appalling pollution but also with substantial cost burdens of future remediation.

    In late 2004, an Environmental Impact Statement was completed for the Groundwater Treatment Plant. The proposed treatment is by incineration and has been opposed by NGOs and the local community.

    (See NTN submission to the EIS) Word 109k

     

     




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